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Effect of solvent composition on the van't Hoff enthalpic curve using amylose 3,5-dichlorophenylcarbamate-based sorbent.
Lin AY, Cheng KT, Chen SC, Tsui HW. Lin AY, et al. J Chromatogr A. 2017 Sep 15;1515:179-186. doi: 10.1016/j.chroma.2017.08.011. Epub 2017 Aug 4. J Chromatogr A. 2017. PMID: 28803646
Van't Hoff plots have been widely used for investigating the thermodynamic properties of adsorption processes in various chromatography systems. ...As a result, the shapes of van't Hoff enthalpic curves reflect the adsorption isotherm …
Van't Hoff plots have been widely used for investigating the thermodynamic properties of adsorption processes in variou …
Thermodynamics of protein-ligand interactions as a reference for computational analysis: how to assess accuracy, reliability and relevance of experimental data.
Krimmer SG, Klebe G. Krimmer SG, et al. J Comput Aided Mol Des. 2015 Sep;29(9):867-83. doi: 10.1007/s10822-015-9867-y. Epub 2015 Sep 16. J Comput Aided Mol Des. 2015. PMID: 26376645 Review.
The aim of this article is to provide the reader with basic understanding of the ITC technique and the experimental practices commonly applied, in order to foster an appreciation for how much measured thermodynamic parameters can deviate from ideal, error-free values. Particular …
The aim of this article is to provide the reader with basic understanding of the ITC technique and the experimental practices commonly appli …
Cato Guldberg and Peter Waage, the history of the Law of Mass Action, and its relevance to clinical pharmacology.
Ferner RE, Aronson JK. Ferner RE, et al. Br J Clin Pharmacol. 2016 Jan;81(1):52-5. doi: 10.1111/bcp.12721. Epub 2015 Oct 22. Br J Clin Pharmacol. 2016. PMID: 26174880 Free PMC article. Review.
The Law evolved from the work of the French chemist Claude Louis Berthollet, was first formulated by Cato Guldberg and Peter Waage in 1864 and later clarified by the Dutch chemist Jacobus van 't Hoff in 1877. It has profoundly influenced our qualitative and q …
The Law evolved from the work of the French chemist Claude Louis Berthollet, was first formulated by Cato Guldberg and Peter Waage in 1864 a …
Carbyne Ring Activated Using ZnCl2 for Hydrogen Adsorption: DFT Study.
Desales Guzmán LA, Pacheco Sánchez JH, Arellano Peraza JS. Desales Guzmán LA, et al. ACS Omega. 2022 Mar 16;7(12):10100-10114. doi: 10.1021/acsomega.1c06149. eCollection 2022 Mar 29. ACS Omega. 2022. PMID: 35382298 Free PMC article.
(v) Equilibrium pressure for CaC(12)-7H(2) and Ca(3)C(12)-21H(2) systems (5-15 MPa) by means of adsorption isotherm calculations. The calculated van't Hoff desorption temperatures exceed considerably the boiling point of liquid nitrogen. ...
(v) Equilibrium pressure for CaC(12)-7H(2) and Ca(3)C(12)-21H(2) systems (5-15 MPa) by means of adsorption isotherm calculations. The …
Mechanisms of halosulfuron methyl pesticide biosorption onto neem seeds powder.
Haq AU, Saeed M, Usman M, Zahoor AF, Anjum MN, Maqbool T, Naheed S, Kashif M. Haq AU, et al. Sci Rep. 2021 May 11;11(1):9960. doi: 10.1038/s41598-021-88929-7. Sci Rep. 2021. PMID: 33976253 Free PMC article.
Kinetics of halosulfuron methyl were demonstrated well by pseudo second order due to highest R(2) (0.99) owing to the nearness between experimental and calculated sorption capacities. Isotherm results imply that Langmuir was found to the principal model to explain the remo …
Kinetics of halosulfuron methyl were demonstrated well by pseudo second order due to highest R(2) (0.99) owing to the nearness between exper …
Thermodynamic parameters of ligand-receptor interactions: computation and error margins.
Pliska V. Pliska V. J Recept Signal Transduct Res. 1997 Jan-May;17(1-3):495-510. doi: 10.3109/10799899709036623. J Recept Signal Transduct Res. 1997. PMID: 9029510 Review.
A semiempirical relationship describing the temperature function of ligand-receptor dissociation constants (Kd), derived from heat capacities of the system in equilibrium, is suggested for computation of the standard enthalpy (delta H degree) and standard entropy (delta S degree) …
A semiempirical relationship describing the temperature function of ligand-receptor dissociation constants (Kd), derived from heat capacitie …
Removal of Cr(VI) by biochar derived via co-pyrolysis of oily sludge and corn stalks.
Han L, Li J, Zhang T, Qu C, Yu T, Yang B, Shao Z. Han L, et al. Sci Rep. 2022 Jun 14;12(1):9821. doi: 10.1038/s41598-022-14142-9. Sci Rep. 2022. PMID: 35701474 Free PMC article.
In addition, the removal process was discussed, and the results indicated that the McKay kinetic model, Langmuir isotherm model and Van't Hoff thermodynamic model were the most suitable models for removal. ...
In addition, the removal process was discussed, and the results indicated that the McKay kinetic model, Langmuir isotherm model and …
Is there a difference between surfactant-stabilised and Pickering emulsions?
Dekker RI, Velandia SF, Kibbelaar HVM, Morcy A, Sadtler V, Roques-Carmes T, Groenewold J, Kegel WK, Velikov KP, Bonn D. Dekker RI, et al. Soft Matter. 2023 Mar 8;19(10):1941-1951. doi: 10.1039/d2sm01375d. Soft Matter. 2023. PMID: 36808176
We analyse the surface tension data using the Gibbs adsorption isotherm and the Langmuir equation of state for the surface, resulting in surprisingly high adsorption densities for the particle-based systems. ...
We analyse the surface tension data using the Gibbs adsorption isotherm and the Langmuir equation of state for the surface, resulting …
Solvent effects on the retention mechanisms of an amylose-based sorbent.
Tsui HW, Cheng KT, Lin AY, Chen SC, Hung YL, Chou PY. Tsui HW, et al. J Chromatogr A. 2018 Jun 29;1556:64-72. doi: 10.1016/j.chroma.2018.04.065. Epub 2018 Apr 27. J Chromatogr A. 2018. PMID: 29731289
The thermodynamic properties of adsorption for the four modifiers were thoroughly investigated using retention factor data, van't Hoff plots, and adsorption isotherms of the modifier molecules. The adsorption data of acetone and isopropanol followed the Langm …
The thermodynamic properties of adsorption for the four modifiers were thoroughly investigated using retention factor data, van't …
Novel, Environment-Friendly Cellulose-Based Derivatives for Tetraconazole Removal from Aqueous Solution.
Khalaf B, Hamed O, Jodeh S, Hanbali G, Bol R, Dagdag O, Samhan S. Khalaf B, et al. Polymers (Basel). 2021 Jan 30;13(3):450. doi: 10.3390/polym13030450. Polymers (Basel). 2021. PMID: 33573294 Free PMC article.
The adsorption kinetics were also investigated using pseudo-first-order, pseudo-second-order, and intra-particle-diffusion adsorption kinetic models. The Van't Hoff plot was also studied for each adsorption to determine the changes in adsorption enthalpy (H), …
The adsorption kinetics were also investigated using pseudo-first-order, pseudo-second-order, and intra-particle-diffusion adsorption kineti …
66 results