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Unknown field was ignored: [1,3-dihydroquinazoline-2,5'-azepane]
Page 1
Synthesis and oxidation behavior of 2,4,5,7,8-pentamethyl-4H-1,3-benzodioxin-6-ol, a multifunctional oxatocopherol-type antioxidant.
J Org Chem. 2002 May 31;67(11):3607-14. doi: 10.1021/jo016125j.
J Org Chem. 2002.
PMID: 12027671
In aqueous media, 1 is oxidized by one oxidation equivalent to 2,5-dihydroxy-3,4,6-trimethylacetophenone (3) via 2-(1-hydroxyethyl)-3,5,6-trimethylbenzo-1,4-quinone (2). The acid-catalyzed conversion of 2 into 3 proceeds in solution with …
In aqueous media, 1 is oxidized by one oxidation equivalent to 2,5-dihydroxy-3,4,6-trimethylacetophenone (3) via 2-(1-hydroxye …
Mechanism of metabolic activation and DNA adduct formation by the human carcinogen diethylstilbestrol: the defining link to natural estrogens.
Saeed M, Rogan E, Cavalieri E.
Saeed M, et al.
Int J Cancer. 2009 Mar 15;124(6):1276-84. doi: 10.1002/ijc.24113.
Int J Cancer. 2009.
PMID: 19089919
Free PMC article.
DES is mainly metabolized to its catechol, 3'-hydroxyDES (3'-OH-DES), which can further oxidize to DES-3',4'-quinone (DES-3',4'-Q). Similarly to estradiol-3,4-quinone, the reaction of DES-3',4'-Q with DNA would form the depurinating 3'-OH-DES-6'-N3Ade …
DES is mainly metabolized to its catechol, 3'-hydroxyDES (3'-OH-DES), which can further oxidize to DES-3',4'-quinone (DES-3',4 …
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Solvent influence on model oxidations of alpha-tocopherol.
Sumarno M, Atkinson E, Suarna C, Saunders JK, Cole ER, Southwell-Keely PT.
Sumarno M, et al.
Biochim Biophys Acta. 1987 Aug 15;920(3):247-50. doi: 10.1016/0005-2760(87)90101-9.
Biochim Biophys Acta. 1987.
PMID: 3607079
Inclusion of a small amount of ethanol in the reaction mixture brought about immediate oxidation and the formation of a new product, 5-ethoxymethyl-7,8-dimethyltocol in addition to the spiro dimer and spiro trimer of alpha-tocopherol, alpha-tocopherylquinone and 5-f …
Inclusion of a small amount of ethanol in the reaction mixture brought about immediate oxidation and the formation of a new product, 5-ethox …
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