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Page 1
Heterometal-Doped M(23) (M = Au/Ag/Cd) Nanoclusters with Large Dipole Moments.
Li Y, Cowan MJ, Zhou M, Taylor MG, Wang H, Song Y, Mpourmpakis G, Jin R. Li Y, et al. ACS Nano. 2020 Jun 23;14(6):6599-6606. doi: 10.1021/acsnano.0c01000. Epub 2020 Apr 21. ACS Nano. 2020. PMID: 32286795
Herein, we report a doping strategy to give giant dipoles (18 D) in M(23) (M = Au/Ag/Cd) NCs, falling in the experimental trend for II-VI quantum dots. In M(23) NCs, high mu is caused by the Cd-Br bond and the arrangement of heteroatoms along the C(3) axis. . …
Herein, we report a doping strategy to give giant dipoles (18 D) in M(23) (M = Au/Ag/Cd) NCs, falling in the experimental tren …
Walking in multiple sclerosis improves with tDCS: a randomized, double-blind, sham-controlled study.
Pilloni G, Choi C, Shaw MT, Coghe G, Krupp L, Moffat M, Cocco E, Pau M, Charvet L. Pilloni G, et al. Ann Clin Transl Neurol. 2020 Nov;7(11):2310-2319. doi: 10.1002/acn3.51224. Epub 2020 Oct 20. Ann Clin Transl Neurol. 2020. PMID: 33080122 Free PMC article. Clinical Trial.

The active group had a significantly greater increase in gait speed (0.87 vs. 1.20 m/s, p < 0.001) and distance covered during the 2-minute walking test (118.53 vs. 133.06 m, p < 0.001) at intervention end compared to baseline. At 4-week follow-up, these impro

…

The active group had a significantly greater increase in gait speed (0.87 vs. 1.20 m/s, p < 0.001) and distance covered during the

…
Transition metal embedded C3N monolayers as promising catalysts for the hydrogen evolution reaction.
Zhao Y , Ma D , Zhang J , Lu Z , Wang Y . Zhao Y , et al. Phys Chem Chem Phys. 2019 Sep 18;21(36):20432-20441. doi: 10.1039/c9cp04267a. Phys Chem Chem Phys. 2019. PMID: 31502629
By using first-principles calculations, the TM-embedded C3N monolayer (TM@C3N) has been theoretically investigated for HER, for which eighteen TMs are selected from the 3d, 4d, and 5d rows. The M-CC catalysts, with the TM atom embedded into the C-C double atomic vac …
By using first-principles calculations, the TM-embedded C3N monolayer (TM@C3N) has been theoretically investigated for HER, for which eighte …
Novel functional M1 selective muscarinic agonists. Synthesis and structure-activity relationships of 3-(1,2,5-thiadiazolyl)-1,2,5,6-tetrahydro-1-methylpyridines.
Sauerberg P, Olesen PH, Nielsen S, Treppendahl S, Sheardown MJ, Honoré T, Mitch CH, Ward JS, Pike AJ, Bymaster FP, et al. Sauerberg P, et al. J Med Chem. 1992 Jun 12;35(12):2274-83. doi: 10.1021/jm00090a019. J Med Chem. 1992. PMID: 1613751
Selected compounds were also tested for M3 activity in the isolated guinea pig ileum. The C1-8 alkoxy-TZTP 5a-l analogues all displaced [3H]-Oxo-M and [3H]-Pz with low nanomolar affinity. Depicting chain length against Oxo-M binding and against Pz binding the unbran …
Selected compounds were also tested for M3 activity in the isolated guinea pig ileum. The C1-8 alkoxy-TZTP 5a-l analogues all displaced [3H] …
Intercalation of the (1R,2S,3R,4S)-N6-[1-(1,2,3,4-tetrahydro-2,3,4-trihydroxybenz[a]anthracenyl)]-2'-deoxyadenosyl adduct in the N-ras codon 61 sequence: DNA sequence effects.
Li Z, Tamura PJ, Wilkinson AS, Harris CM, Harris TM, Stone MP. Li Z, et al. Biochemistry. 2001 Jun 12;40(23):6743-55. doi: 10.1021/bi002785r. Biochemistry. 2001. PMID: 11389588
-Y., Tamura, P. J., Harris, C. M., Harris, T. M., and Stone, M. P. (1999) Biochemistry 38, 2969-2981], but was similar to the benzo[a]pyrene BP SRSR (61,3) adduct [Zegar I. S., Chary, P., Jabil, R. J., Tamura, P. J., Johansen, T. N., Lloyd, R. S., Harris, C. …
-Y., Tamura, P. J., Harris, C. M., Harris, T. M., and Stone, M. P. (1999) Biochemistry 38, 2969-2981], but was similar …
Characterizing the effect of UDP-glucuronosyltransferase (UGT) 2B7 and UGT1A9 genetic polymorphisms on enantioselective glucuronidation of flurbiprofen.
Wang H, Yuan L, Zeng S. Wang H, et al. Biochem Pharmacol. 2011 Dec 1;82(11):1757-63. doi: 10.1016/j.bcp.2011.08.004. Epub 2011 Aug 11. Biochem Pharmacol. 2011. PMID: 21856293
However, no significantly stereoselective difference for the formation of (R)- and (S)-FPFG was found among these UGT2B7 allozymes. UGT1A9*2 (C(3)Y) exhibited a higher V(max) (3.2-fold), K(m) (2.1-fold) and intrinsic clearance (1.6-fold) toward (S)-FPF than UGT1A9*1 (wild- …
However, no significantly stereoselective difference for the formation of (R)- and (S)-FPFG was found among these UGT2B7 allozymes. UGT1A9*2 …
Crystal structure of bifunctional aldos-2-ulose dehydratase/isomerase from Phanerochaete chrysosporium with the reaction intermediate ascopyrone M.
Claesson M, Lindqvist Y, Madrid S, Sandalova T, Fiskesund R, Yu S, Schneider G. Claesson M, et al. J Mol Biol. 2012 Apr 6;417(4):279-93. doi: 10.1016/j.jmb.2012.02.001. Epub 2012 Feb 8. J Mol Biol. 2012. PMID: 22330145 Free article.
The structure of the Zn(2)(+)-depleted enzyme is very similar to that of native AUDH, and structural changes upon metal removal as the cause for the catalytic deficiencies can be excluded. The complex with the reaction intermediate ascopyrone M shows binding of this compou …
The structure of the Zn(2)(+)-depleted enzyme is very similar to that of native AUDH, and structural changes upon metal removal as the cause …
A proposed set of metrics for standardized outcome reporting in the management of low back pain.
Clement RC, Welander A, Stowell C, Cha TD, Chen JL, Davies M, Fairbank JC, Foley KT, Gehrchen M, Hagg O, Jacobs WC, Kahler R, Khan SN, Lieberman IH, Morisson B, Ohnmeiss DD, Peul WC, Shonnard NH, Smuck MW, Solberg TK, Stromqvist BH, Hooff ML, Wasan AD, Willems PC, Yeo W, Fritzell P. Clement RC, et al. Acta Orthop. 2015;86(5):523-33. doi: 10.3109/17453674.2015.1036696. Acta Orthop. 2015. PMID: 25828191 Free PMC article.
RESULTS: Patient-reported metrics include numerical pain scales, lumbar-related function using the Oswestry disability index, health-related quality of life using the EQ-5D-3L questionnaire, and questions assessing work status and analgesic use. ...
RESULTS: Patient-reported metrics include numerical pain scales, lumbar-related function using the Oswestry disability index, health-related …
Base-Displaced Intercalated Conformation of the 2-Amino-3-methylimidazo[4,5-f]quinoline N(2)-dG DNA Adduct Positioned at the Nonreiterated G(1) in the NarI Restriction Site.
Stavros KM, Hawkins EK, Rizzo CJ, Stone MP. Stavros KM, et al. Chem Res Toxicol. 2015 Jul 20;28(7):1455-68. doi: 10.1021/acs.chemrestox.5b00140. Epub 2015 Jun 17. Chem Res Toxicol. 2015. PMID: 26083477 Free PMC article.
The structure of the N(2)-dG-IQ adduct at the nonreiterated G(1) position was compared to that of the same adduct placed at the G(3) position [Stavros, K. M., et al. (2014) Nucleic Acids Res., 42, 3450-3463]. CD indicted minimal spectral differences between the G(1) vs G(3 …
The structure of the N(2)-dG-IQ adduct at the nonreiterated G(1) position was compared to that of the same adduct placed at the G(3) positio …
Effects of N on plant response to heat-wave: a field study with prairie vegetation.
Wang D, Heckathorn SA, Mainali K, Hamilton EW. Wang D, et al. J Integr Plant Biol. 2008 Nov;50(11):1416-25. doi: 10.1111/j.1744-7909.2008.00748.x. J Integr Plant Biol. 2008. PMID: 19017129
HS (5 d at ambient or 40.5 degrees C) and N treatments (+/-N) were applied to 16 1 m(2) plots in restored prairie vegetation dominated by Andropogon gerardii (warm-season C4 grass) and Solidago canadensis (warm-season C3 forb). ...
HS (5 d at ambient or 40.5 degrees C) and N treatments (+/-N) were applied to 16 1 m(2) plots in restored prairie vegetation dominate …
19 results