Abstract
Trimethylsilylethynyl ketones can be desilylated in the presence of a tethered carbon diacid and induced to undergo a double Michael reaction in situ. The trimethylsilylethynyl ketones can serve as surrogates of ethynyl ketones that are difficult to prepare or isolate.
Publication types
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Comparative Study
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
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Research Support, U.S. Gov't, P.H.S.
MeSH terms
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Alkanes / chemical synthesis
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Alkanes / chemistry
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Catalysis
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Ketones / chemical synthesis*
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Ketones / chemistry*
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Magnetic Resonance Spectroscopy
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Molecular Structure
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Silanes / chemical synthesis
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Silanes / chemistry
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Stereoisomerism