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Nanoscale Res Lett. 2013 Mar 28;8(1):146. doi: 10.1186/1556-276X-8-146.

Silica nanoparticles as a tool for fluorescence collection efficiency enhancement.

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  • 1Institute of Physics, Nicolaus Copernicus University, Grudziadzka 5, Torun 87-100, Poland.


In this work we demonstrate enhancement of the fluorescence collection efficiency for chlorophyll-containing photosynthetic complexes deposited on SiO2 spherical nanoparticles. Microscopic images of fluorescence emission reveal ring-like emission patterns associated with chlorophyll-containing complexes coupled to electromagnetic modes within the silica nanoparticles. The interaction leaves no effect upon the emission spectra of the complexes, and the transient behavior of the fluorescence also remains unchanged, which indicates no influence of the silica nanoparticles on the radiative properties of the fluorophores. We interpret this enhancement as a result of efficient scattering of electromagnetic field by the dielectric nanoparticles that increases collection efficiency of fluorescence emission.

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