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Chem Soc Rev. 2013 Feb 21;42(4):1440-59. doi: 10.1039/c2cs35228a. Epub 2012 Sep 13.

Redox-active ligands in catalysis.

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  • 1Yale Chemistry Dept. and Energy Sciences Institute, P.O. Box 208107, 225 Prospect St., New Haven, CT 06520-8107, USA.

Abstract

Odd-electron, redox-active ligands are discussed in the context of catalysis. We focus on ligand-based, non-singlet state intermediates and their participation in catalytic processes and related stoichiometric transformations.

PMID:
22975722
[PubMed]
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