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J Am Chem Soc. 2011 Oct 5;133(39):15350-3. doi: 10.1021/ja207386q. Epub 2011 Sep 8.

Asymmetric synthesis of ageliferin.

Author information

  • 1Division of Chemistry, Department of Biochemistry, The University of Texas Southwestern Medical Center at Dallas, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038, United States.

Abstract

We describe herein an asymmetric synthesis of ageliferin. A Mn(III)-mediated oxidative radical cyclization reaction was used as the key step to construct the core skeleton of this pyrrole-imidazole dimer. This approach resembles the biogenic [4 + 2] dimerization in an intramolecular fashion.

PMID:
21888421
[PubMed - indexed for MEDLINE]
PMCID:
PMC3183238
Free PMC Article

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