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Page 1
Health-related quality of life in patients with microsatellite instability-high or mismatch repair deficient metastatic colorectal cancer treated with first-line pembrolizumab versus chemotherapy (KEYNOTE-177): an open-label, randomised, phase 3 trial.
Andre T, Amonkar M, Norquist JM, Shiu KK, Kim TW, Jensen BV, Jensen LH, Punt CJA, Smith D, Garcia-Carbonero R, Sevilla I, De La Fouchardiere C, Rivera F, Elez E, Diaz LA Jr, Yoshino T, Van Cutsem E, Yang P, Farooqui M, Le DT. Andre T, et al. Lancet Oncol. 2021 May;22(5):665-677. doi: 10.1016/S1470-2045(21)00064-4. Epub 2021 Apr 1. Lancet Oncol. 2021. PMID: 33812497 Clinical Trial.
HRQOL outcomes were mean change from baseline to prespecified week 18 in European Organisation for Research and Treatment of Cancer Quality of Life Questionnaire Core 30 (EORTC QLQ-C30) and EORTC Quality of Life Questionnaire-Colorectal 29 (EORTC QLQ-CR29) scale and item scores, …
HRQOL outcomes were mean change from baseline to prespecified week 18 in European Organisation for Research and Treatment of Cancer Quality …
Er(3+) Photoluminescence in Er(2)@C(82) and Er(2)C(2)@C(82) Metallofullerenes Elucidated by Density Functional Theory.
Wang J, Zhao YY, Lee PH, Irle S. Wang J, et al. Inorg Chem. 2017 Jun 5;56(11):6576-6583. doi: 10.1021/acs.inorgchem.7b00695. Epub 2017 May 24. Inorg Chem. 2017. PMID: 28537743
The calculations suggest that erbium atoms assume a trivalent state with Er (4f(11)) valence electronic configuration in Er(2)@C(82) and Er(2)C(2)@C(82), where two electrons (6s(2)) per Er atom are transferred to the cage carrying four negative charges …
The calculations suggest that erbium atoms assume a trivalent state with Er (4f(11)) valence electronic configuration in Er(2) …
Ab Initio Crystal Field for Lanthanides.
Ungur L, Chibotaru LF. Ungur L, et al. Chemistry. 2017 Mar 13;23(15):3708-3718. doi: 10.1002/chem.201605102. Epub 2017 Feb 20. Chemistry. 2017. PMID: 27983776
It is shown how the predictions of standard CASSCF (Complete Active Space Self-Consistent Field) calculations (with 4f orbitals in the active space) can be systematically improved by including effects of dynamical electronic correlation (CASPT2 step) and by admixing electronic co …
It is shown how the predictions of standard CASSCF (Complete Active Space Self-Consistent Field) calculations (with 4f orbitals in the activ …
Design, synthesis, in vitro and in silico evaluation of indole-based tetrazole derivatives as putative anti-breast cancer agents.
Kaur K, Verma H, Gangwar P, Dhiman M, Jaitak V. Kaur K, et al. RSC Med Chem. 2024 Feb 19;15(4):1329-1347. doi: 10.1039/d3md00730h. eCollection 2024 Apr 24. RSC Med Chem. 2024. PMID: 38665833
The compounds exhibited in vitro anti-proliferative activity against ER-alpha positive T-47D (IC(50) = 3.82-24.43 muM), MCF-7 (IC(50) = 3.08-22.65 muM), and ER-alpha negative MDA-MB-231 (IC(50) = 7.69-19.4 muM) human breast cancer cell lines. ...Western blot …
The compounds exhibited in vitro anti-proliferative activity against ER-alpha positive T-47D (IC(50) = 3.82-24.43 muM), MCF-7 (IC(50) …
Are lanthanide-transition metal direct bonds a route to achieving new generation {3d-4f} SMMs?
Swain A, Sen A, Rajaraman G. Swain A, et al. Dalton Trans. 2021 Nov 16;50(44):16099-16109. doi: 10.1039/d1dt02256c. Dalton Trans. 2021. PMID: 34647556
Bonding analysis reveals a dative Ln-TM bond with a donation of pi(V/Mnd(xy)-pi*CO) to 5d(z(2)) (Gd) in the case of Gd-V and Gd-Mn and 4s(Co) to 5d(xy)/5d(yz) (Gd) for Gd-Co with the transition metal ion being found in the low-spin S = configurations in all t …
Bonding analysis reveals a dative Ln-TM bond with a donation of pi(V/Mnd(xy)-pi*CO) to 5d(z(2)) (Gd) in the case of Gd-V and Gd-Mn an …
Evaluating electrochemical accessibility of 4f(n)5d(1) and 4f(n+1) Ln(II) ions in (C(5)H(4)SiMe(3))(3)Ln and (C(5)Me(4)H)(3)Ln complexes.
Trinh MT, Wedal JC, Evans WJ. Trinh MT, et al. Dalton Trans. 2021 Oct 19;50(40):14384-14389. doi: 10.1039/d1dt02427b. Dalton Trans. 2021. PMID: 34569559
The Ln(III)/Ln(II) reduction potentials for Ln = Eu, Yb, Sm, and Tm (-1.07 to -2.83 V) follow the expected trend for stability of 4f(7), 4f(14), 4f(6), and 4f(13) Ln(II) ions, respectively. The reduction potentials for Ln = Pr, Nd, Gd, Tb, Dy, Ho, Er, and Lu, that form 4f( …
The Ln(III)/Ln(II) reduction potentials for Ln = Eu, Yb, Sm, and Tm (-1.07 to -2.83 V) follow the expected trend for stability of 4f(7), 4f( …
Human-Specific Regulation of Neurotrophic Factors MANF and CDNF by microRNAs.
Konovalova J, Gerasymchuk D, Arroyo SN, Kluske S, Mastroianni F, Pereyra AV, Domanskyi A. Konovalova J, et al. Int J Mol Sci. 2021 Sep 7;22(18):9691. doi: 10.3390/ijms22189691. Int J Mol Sci. 2021. PMID: 34575854 Free PMC article.
Furthermore, we demonstrate a functional effect of miR-144 mediated regulation of MANF on ER stress response markers. These findings emphasize that (1) prediction of miRNA targets based on evolutionary conservation may miss biologically meaningful regulatory pairs; and (2) …
Furthermore, we demonstrate a functional effect of miR-144 mediated regulation of MANF on ER stress response markers. These findings …
Evaluating the electronic structure of formal LnII ions in LnII(C5H4SiMe3)31- using XANES spectroscopy and DFT calculations.
Fieser ME, Ferrier MG, Su J, Batista E, Cary SK, Engle JW, Evans WJ, Lezama Pacheco JS, Kozimor SA, Olson AC, Ryan AJ, Stein BW, Wagner GL, Woen DH, Vitova T, Yang P. Fieser ME, et al. Chem Sci. 2017 Sep 1;8(9):6076-6091. doi: 10.1039/c7sc00825b. Epub 2017 Jun 30. Chem Sci. 2017. PMID: 28989638 Free PMC article.
Additionally, our results suggest that Ln(C(5)H(4)SiMe(3))(3)(1-) (Ln = Pr, Nd, Gd, Tb, Dy, Ho, and Er) also contain Ln(II) ions, but with 4f (n) 5d(1) configurations (not 4f (n+1) 5d(0)). In these 4f (n) 5d(1) complexes, the C(3h)-symmetric ligand env …
Additionally, our results suggest that Ln(C(5)H(4)SiMe(3))(3)(1-) (Ln = Pr, Nd, Gd, Tb, Dy, Ho, and Er) also contain Ln(II) ions, but …
Reconfigurable TE-pass polarizer based on lithium niobate waveguide assisted by Ge2Sb2Te5 and silicon nitride.
Fei Y, Xu Y, Dong Y, Zhang B, Ni Y. Fei Y, et al. Appl Opt. 2023 Aug 20;62(24):6499-6506. doi: 10.1364/AO.496942. Appl Opt. 2023. PMID: 37706844
The proposed device length is 7.5 m with an insertion loss (IL)=0.22 dB and extinction ratio (ER)=32.8 dB at the wavelength of 1550 nm. Moreover, it also has a high ER (>25d B) and a low IL (<0.5d B) in the operating bandwidth of 200 nm. ...
The proposed device length is 7.5 m with an insertion loss (IL)=0.22 dB and extinction ratio (ER)=32.8 dB at the wavelength of …
[Clinical characteristics and risk factors of recurrent Kawasaki disease].
Tan AX, Tang XM. Tan AX, et al. Zhonghua Er Ke Za Zhi. 2021 Dec 2;59(12):1038-1042. doi: 10.3760/cma.j.cn112140-20210827-00710. Zhonghua Er Ke Za Zhi. 2021. PMID: 34856662 Chinese.
Compared with the first episode, the second episode had lower white blood cell count (15.2 (12.8-18.8)10(9) vs. 18.0 (14.9-23.4)10(9)/L, Z=-2.462, P=0.014) and rate of edema in extremities (54% (22/41) vs. 76% (31/41), chi(2)=4.321, P=0.038), shorter fever durations before …
Compared with the first episode, the second episode had lower white blood cell count (15.2 (12.8-18.8)10(9) vs. 18.0 (14.9-23.4)10(9)/L, Z=- …
40 results