Evaluating the electronic structure of formal LnII ions in LnII(C5H4SiMe3)31- using XANES spectroscopy and DFT calculations.
Fieser ME, Ferrier MG, Su J, Batista E, Cary SK, Engle JW, Evans WJ, Lezama Pacheco JS, Kozimor SA, Olson AC, Ryan AJ, Stein BW, Wagner GL, Woen DH, Vitova T, Yang P.
Fieser ME, et al.
Chem Sci. 2017 Sep 1;8(9):6076-6091. doi: 10.1039/c7sc00825b. Epub 2017 Jun 30.
Chem Sci. 2017.
PMID: 28989638
Free PMC article.
Additionally, our results suggest that Ln(C(5)H(4)SiMe(3))(3)(1-) (Ln = Pr, Nd, Gd, Tb, Dy, Ho, and Er) also contain Ln(II) ions, but with 4f (n) 5d(1) configurations (not 4f (n+1) 5d(0)). In these 4f (n) 5d(1) complexes, the C(3h)-symmetric ligand env …
Additionally, our results suggest that Ln(C(5)H(4)SiMe(3))(3)(1-) (Ln = Pr, Nd, Gd, Tb, Dy, Ho, and Er) also contain Ln(II) ions, but …