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Chem Commun (Camb). 2002 Apr 21;(8):892-3.

Electrodeposition of stable and narrowly dispersed germanium nanoclusters from an ionic liquid.

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  • 1University of Karlsruhe, Institute for Physical Chemistry, D-76128 Karlsruhe, Germany.


Germanium nanoclusters with a narrow height distribution have been electrodeposited from a dilute solution of GeCl4 in the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate [BMIm]PF6: under the reported conditions the lateral sizes of most of the clusters range between 20 and 30 nm while their heights vary from 1 to 10 nm with most of them between 1 and 5 nm.

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