Format

Send to:

Choose Destination

Similar articles for PubMed (Select 23232493)

See comment in PubMed Commons below
Dalton Trans. 2013 Feb 28;42(8):2813-6. doi: 10.1039/c2dt32779a.

Oxidative purification of halogenated ferrocenes.

Author information

  • 1Department of Chemistry, Imperial College London, London SW7 2AZ, UK.

Abstract

We report the large scale syntheses and 'oxidative purification' of fcI(2), fcBr(2) and FcBr (fc = ferrocene-1,1'-diyl, Fc = ferrocenyl). These valuable starting materials are typically laborious to separate via conventional techniques, but can be readily isolated by taking advantage of their increased E(1/2) relative to FcH/FcX contaminants. Our work extends this methodology towards a generic tool for the separation of redox active mixtures.

PMID:
23232493
[PubMed - indexed for MEDLINE]
PubMed Commons home

PubMed Commons

0 comments
How to join PubMed Commons

    Supplemental Content

    Full text links

    Icon for Royal Society of Chemistry
    Loading ...
    Write to the Help Desk