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Results: 1 to 20 of 103

1.

Hydroxylation mechanism of methane and its derivatives over designed methane monooxygenase model with peroxo dizinc core.

Li CQ, Yang HQ, Xu J, Hu CW.

Org Biomol Chem. 2012 May 21;10(19):3924-31. doi: 10.1039/c2ob25163a. Epub 2012 Apr 11.

PMID:
22495218
[PubMed - indexed for MEDLINE]
2.
3.

Oxidation reactions performed by soluble methane monooxygenase hydroxylase intermediates H(peroxo) and Q proceed by distinct mechanisms.

Tinberg CE, Lippard SJ.

Biochemistry. 2010 Sep 14;49(36):7902-12. doi: 10.1021/bi1009375.

PMID:
20681546
[PubMed - indexed for MEDLINE]
Free PMC Article
4.

Theoretical study on the gas-phase reaction mechanism between palladium monoxide and methane.

Yang HQ, Hu CW, Gao C, Yang MY, Li FM, Li CQ, Li XY.

J Comput Chem. 2011 Dec;32(16):3440-55. doi: 10.1002/jcc.21926. Epub 2011 Sep 15.

PMID:
21919016
[PubMed - indexed for MEDLINE]
5.

Hydroxylation catalysis by mononuclear and dinuclear iron oxo catalysts: a methane monooxygenase model system versus the Fenton reagent Fe(IV)O(H2O)5(2+).

Gopakumar G, Belanzoni P, Baerends EJ.

Inorg Chem. 2012 Jan 2;51(1):63-75. doi: 10.1021/ic200754w. Epub 2011 Dec 19.

PMID:
22221279
[PubMed - indexed for MEDLINE]
6.

Kinetics and activation thermodynamics of methane monooxygenase compound Q formation and reaction with substrates.

Brazeau BJ, Lipscomb JD.

Biochemistry. 2000 Nov 7;39(44):13503-15.

PMID:
11063587
[PubMed - indexed for MEDLINE]
7.

Stereospecific alkane hydroxylation by non-heme iron catalysts: mechanistic evidence for an Fe(V)=O active species.

Chen K, Que L Jr.

J Am Chem Soc. 2001 Jul 4;123(26):6327-37.

PMID:
11427057
[PubMed - indexed for MEDLINE]
8.

Hydroxylation of methane by non-heme diiron enzymes: molecular orbital analysis of C-H bond activation by reactive intermediate Q.

Baik MH, Gherman BF, Friesner RA, Lippard SJ.

J Am Chem Soc. 2002 Dec 11;124(49):14608-15.

PMID:
12465971
[PubMed - indexed for MEDLINE]
9.

DFT study of the mechanism for methane hydroxylation by soluble methane monooxygenase (sMMO): effects of oxidation state, spin state, and coordination number.

Huang SP, Shiota Y, Yoshizawa K.

Dalton Trans. 2013 Jan 28;42(4):1011-23. doi: 10.1039/c2dt31304a.

PMID:
23108153
[PubMed - indexed for MEDLINE]
10.

Two-step concerted mechanism for methane hydroxylation on the diiron active site of soluble methane monooxygenase.

Yoshizawa K.

J Inorg Biochem. 2000 Jan 15;78(1):23-34.

PMID:
10714702
[PubMed - indexed for MEDLINE]
11.

Substrate hydroxylation in methane monooxygenase: quantitative modeling via mixed quantum mechanics/molecular mechanics techniques.

Gherman BF, Lippard SJ, Friesner RA.

J Am Chem Soc. 2005 Jan 26;127(3):1025-37.

PMID:
15656641
[PubMed - indexed for MEDLINE]
12.

Dynamics of alkane hydroxylation at the non-heme diiron center in methane monooxygenase.

Guallar V, Gherman BF, Miller WH, Lippard SJ, Friesner RA.

J Am Chem Soc. 2002 Apr 3;124(13):3377-84.

PMID:
11916423
[PubMed - indexed for MEDLINE]
13.

Dioxygen activation in soluble methane monooxygenase.

Tinberg CE, Lippard SJ.

Acc Chem Res. 2011 Apr 19;44(4):280-8. doi: 10.1021/ar1001473. Epub 2011 Mar 10. Review.

PMID:
21391602
[PubMed - indexed for MEDLINE]
Free PMC Article
14.

Substrate-triggered activation of a synthetic [Fe2(μ-O)2] diamond core for C-H bond cleavage.

Xue G, Pokutsa A, Que L Jr.

J Am Chem Soc. 2011 Oct 19;133(41):16657-67. doi: 10.1021/ja207131g. Epub 2011 Sep 21.

PMID:
21899336
[PubMed - indexed for MEDLINE]
Free PMC Article
15.

An abiotic analogue of the diiron(IV)oxo "diamond core" of soluble methane monooxygenase generated by direct activation of O2 in aqueous Fe(II)/EDTA solutions: thermodynamics and electronic structure.

Bernasconi L, Belanzoni P, Baerends EJ.

Phys Chem Chem Phys. 2011 Sep 7;13(33):15272-82. doi: 10.1039/c1cp21244c. Epub 2011 Jul 21.

PMID:
21776512
[PubMed - indexed for MEDLINE]
16.

Methane monooxygenase component B mutants alter the kinetics of steps throughout the catalytic cycle.

Wallar BJ, Lipscomb JD.

Biochemistry. 2001 Feb 20;40(7):2220-33.

PMID:
11329291
[PubMed - indexed for MEDLINE]
17.

Theoretical modeling of the hydroxylation of methane as mediated by the particulate methane monooxygenase.

Chen PP, Chan SI.

J Inorg Biochem. 2006 Apr;100(4):801-9. Epub 2006 Feb 21.

PMID:
16494948
[PubMed - indexed for MEDLINE]
18.

A non-radical mechanism for methane hydroxylation at the diiron active site of soluble methane monooxygenase.

Yoshizawa K, Yumura T.

Chemistry. 2003 May 23;9(10):2347-58.

PMID:
12772310
[PubMed - indexed for MEDLINE]
20.

Reactions of the peroxo intermediate of soluble methane monooxygenase hydroxylase with ethers.

Beauvais LG, Lippard SJ.

J Am Chem Soc. 2005 May 25;127(20):7370-8.

PMID:
15898785
[PubMed - indexed for MEDLINE]

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