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Transition metal chemistry of cyclodiphosphanes containing phosphine and amide-phosphine functionalities: formation of a stable dipalladium(II) complex containing a Pd-P σ-bond.

Balakrishna MS, Venkateswaran R, Mague JT. Balakrishna MS, et al. Dalton Trans. 2010 Dec 14;39(46):11149-62. doi: 10.1039/c0dt00614a. Epub 2010 Oct 8. Dalton Trans. 2010. PMID: 20936211

An acyclic dimer of cyclodiphosphazane {(t)BuHN((t)BuNP)2OCH2}2 containing alkoxo and amido functionalities: synthesis, derivatization, Bi- (Pd(II), Rh(I)), and tetranuclear (Pd(II), Au(I), Rh(I)Au(I)) transition metal complexes.

Balakrishna MS, Venkateswaran R, Mague JT. Balakrishna MS, et al. Inorg Chem. 2009 Feb 16;48(4):1398-406. doi: 10.1021/ic801256h. Inorg Chem. 2009. PMID: 19133774

Cyclodiphosphazanes with hemilabile ponytails: synthesis, transition metal chemistry (Ru(II), Rh(I), Pd(II), Pt(II)), and crystal and molecular structures of mononuclear (Pd(II), Rh(I)) and bi- and tetranuclear rhodium(I) complexes.

Chandrasekaran P, Mague JT, Balakrishna MS. Chandrasekaran P, et al. Inorg Chem. 2005 Oct 31;44(22):7925-32. doi: 10.1021/ic0509478. Inorg Chem. 2005. PMID: 16241142

Unexpected metal-induced isomerisms and phosphoryl migrations in Pt(II) and Pd(II) complexes of the functional phosphine 2-(bis(diphenylphosphino)methyl)-oxazoline.

Zhang S, Pattacini R, Braunstein P. Zhang S, et al. Inorg Chem. 2011 Apr 18;50(8):3511-22. doi: 10.1021/ic1024422. Epub 2011 Mar 15. Inorg Chem. 2011. PMID: 21405088

Tripodal polyphosphine ligands as inductors of chelate ring-opening processes in mononuclear palladium(II) and platinum(II) compounds. The X-ray crystal structure of two derivatives containing dangling phosphorus.

Fernández-Anca D, García-Seijo MI, García-Fernández ME. Fernández-Anca D, et al. Dalton Trans. 2010 Mar 7;39(9):2327-36. doi: 10.1039/b912678c. Epub 2010 Jan 18. Dalton Trans. 2010. PMID: 20162206

Insertion reactions of alkynes and organic isocyanides into the palladium-carbon bond of dimetallic Fe-Pd alkoxysilyl complexes.

Knorr M, Jourdain I, Braunstein P, Strohmann C, Tiripicchio A, Ugozzoli F. Knorr M, et al. Dalton Trans. 2006 Nov 28;(44):5248-58. doi: 10.1039/b610324c. Epub 2006 Oct 18. Dalton Trans. 2006. PMID: 17088964

New 10-membered inorganic heterocyclic diphosphanes, PhN(PX)(2)[(-OC(6)H(2)((T)Bu)(2))(mu-S)(((t)Bu)(2)C(6)H(2)O-)] (x = cl, f). Synthesis and transition metal complexes (molybdenum(0), ruthenium(II), palladium(II), and platinum(II)) of heterocyclic diphosphanes. crystal and molecular structures of the chloro derivative, PhN(PCl)(2)[(-OC(6)H(2)((t)Bu)(2))(mu-S)(((t)Bu)(2)C(6)H(2)O-)], and of a molybdenum(0) complex of the fluoro derivative, [Mo(CO)(3)[eta(3)-PhN(PF)(2)[(-OC(6)H(2)((t)Bu)(2))(mu-S)(((t)Bu)(2)C(6)H(2)O-)]-kappa P,kappa P,kappa S]].

Balakrishna MS, Panda R, Mague JT. Balakrishna MS, et al. Inorg Chem. 2001 Oct 22;40(22):5620-5. doi: 10.1021/ic010518j. Inorg Chem. 2001. PMID: 11599962

Bis[(2-diphenylphosphino)phenyl]mercury: a P-donor ligand and precursor to mixed metal-mercury (d(8)-d(10)) cyclometalated complexes containing 2-C(6)H(4)PPh(2).

Bennett MA, Contel M, Hockless DC, Welling LL, Willis AC. Bennett MA, et al. Inorg Chem. 2002 Feb 25;41(4):844-55. doi: 10.1021/ic010890z. Inorg Chem. 2002. PMID: 11849085

Carbene-anchored/pendent-imidazolium species as precursors to di-N-heterocyclic carbene-bridged mixed-metal complexes.

Zamora MT, Ferguson MJ, McDonald R, Cowie M. Zamora MT, et al. Dalton Trans. 2009 Sep 21;(35):7269-87. doi: 10.1039/b906884h. Epub 2009 Aug 4. Dalton Trans. 2009. PMID: 20449172

Group 11 metal chemistry of a tetradentate ligand, phenylene-1,4-diaminotetra(phosphonite), p-C6H4[N{P(OC6H4OMe-o)2}2]2.

Ganesamoorthy C, Balakrishna MS, Mague JT. Ganesamoorthy C, et al. Inorg Chem. 2009 Apr 20;48(8):3768-82. doi: 10.1021/ic900085e. Inorg Chem. 2009. PMID: 19317408

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