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Mechanistic study of hydrogen transfer to imines from a hydroxycyclopentadienyl ruthenium hydride. Experimental support for a mechanism involving coordination of imine to ruthenium prior to hydrogen transfer.

Samec JS, Ell AH, Aberg JB, Privalov T, Eriksson L, Bäckvall JE. Samec JS, et al. J Am Chem Soc. 2006 Nov 8;128(44):14293-305. doi: 10.1021/ja061494o. J Am Chem Soc. 2006. PMID: 17076502

Intramolecular trapping of an intermediate in the reduction of imines by a hydroxycyclopentadienyl ruthenium hydride: support for a concerted outer sphere mechanism.

Casey CP, Clark TB, Guzei IA. Casey CP, et al. J Am Chem Soc. 2007 Sep 26;129(38):11821-7. doi: 10.1021/ja073370x. Epub 2007 Aug 31. J Am Chem Soc. 2007. PMID: 17760443

Isomerization and deuterium scrambling evidence for a change in the rate-limiting step during imine hydrogenation by Shvo's hydroxycyclopentadienyl ruthenium hydride.

Casey CP, Johnson JB. Casey CP, et al. J Am Chem Soc. 2005 Feb 16;127(6):1883-94. doi: 10.1021/ja044450t. J Am Chem Soc. 2005. PMID: 15701023

Reduction of imines by hydroxycyclopentadienyl ruthenium hydride: intramolecular trapping evidence for hydride and proton transfer outside the coordination sphere of the metal.

Casey CP, Bikzhanova GA, Cui Q, Guzei IA. Casey CP, et al. J Am Chem Soc. 2005 Oct 12;127(40):14062-71. doi: 10.1021/ja053956o. J Am Chem Soc. 2005. PMID: 16201828

Mechanism of hydrogen transfer to imines from a hydroxycyclopentadienyl ruthenium hydride. Support for a stepwise mechanism.

Samec JS, Ell AH, Bäckvall JE. Samec JS, et al. Chem Commun (Camb). 2004 Dec 7;(23):2748-9. doi: 10.1039/b410698a. Epub 2004 Oct 6. Chem Commun (Camb). 2004. PMID: 15568098

Stereochemistry of imine reduction by a hydroxycyclopentadienyl ruthenium hydride.

Casey CP, Bikzhanova GA, Guzei IA. Casey CP, et al. J Am Chem Soc. 2006 Feb 22;128(7):2286-93. doi: 10.1021/ja056402u. J Am Chem Soc. 2006. PMID: 16478183

Hydrogen elimination from a hydroxycyclopentadienyl ruthenium(II) hydride: study of hydrogen activation in a ligand-metal bifunctional hydrogenation catalyst.

Casey CP, Johnson JB, Singer SW, Cui Q. Casey CP, et al. J Am Chem Soc. 2005 Mar 9;127(9):3100-9. doi: 10.1021/ja043460r. J Am Chem Soc. 2005. PMID: 15740149

Ruthenium-catalyzed transfer hydrogenation of imines by propan-2-ol in benzene.

Samec JS, Bäckvall JE. Samec JS, et al. Chemistry. 2002 Jul 2;8(13):2955-61. doi: 10.1002/1521-3765(20020703)8:13<2955::AID-CHEM2955>3.0.CO;2-Q. Chemistry. 2002. PMID: 12489225

A succession of isomers of ruthenium dihydride complexes. Which one is the ketone hydrogenation catalyst?

Abbel R, Abdur-Rashid K, Faatz M, Hadzovic A, Lough AJ, Morris RH. Abbel R, et al. J Am Chem Soc. 2005 Feb 16;127(6):1870-82. doi: 10.1021/ja039396f. J Am Chem Soc. 2005. PMID: 15701022

Structure and reactivity of bis(silyl) dihydride complexes (PMe(3))(3)Ru(SiR(3))(2)(H)(2): model compounds and real intermediates in a dehydrogenative C-Si bond forming reaction.

Dioumaev VK, Yoo BR, Procopio LJ, Carroll PJ, Berry DH. Dioumaev VK, et al. J Am Chem Soc. 2003 Jul 23;125(29):8936-48. doi: 10.1021/ja035916v. J Am Chem Soc. 2003. PMID: 12862491

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