Enhanced Blocking Effect: A New Strategy to Improve the NO₂ Sensing Performance of Ti₃C₂T_x by γ-Poly(l-glutamic acid) Modification

Titanium carbide (Ti₃C₂T_x) with a distinctive structure, abundant surface chemical groups, and good electrical conductivity has shown great potential in fabricating superior gas sensors, but several challenges, such as low response kinetics, poor reversibility, and serious baseline drift, still remain. In this work, γ-poly(l-glutamic acid) (γ-PGA) with a blocking effect is exploited to modify Ti₃C₂T_x, thereby stimulating the positive response behavior of Ti₃C₂T_x and improving its gas sensing performance. On account of the unique synergetic interaction between Ti₃C₂T_x and γ-PGA, the response of the flexible Ti₃C₂T_x/γ-PGA gas sensor to 50 ppm NO₂has been improved to a large extent (average 1127.3%), which is 85 times that of Ti₃C₂T_x (only 13.2%). Moreover, the as-fabricated Ti₃C₂T_x/γ-PGA sensor not only exhibits a shorter response/recovery time (average 43.4/3 s) compared with the Ti₃C₂T_x-based sensor (∼18.5/18.3 min) but also shows good reversibility and repeatability (relative standard deviation (RSD) <1%) at room temperature within 50% relative humidity (RH). The improved gas sensing properties of the Ti₃C₂T_x/γ-PGA sensor can be attributed to the enhancement of effective adsorption and the blocking effect assisted by water molecules. Furthermore, the gas sensing response of the Ti₃C₂T_x/γ-PGA sensor is studied at different RHs, and humidity compensation of the sensor is carried out using the multiple regression method. This work demonstrates a novel strategy to enhance the gas sensing properties of Ti₃C₂T_x by γ-PGA modification and provides a new way to realize highly responsive gas detection at room temperature.