Synthesis of novel copper-rare earth BINOLate frameworks from a hydrogen bonding DBU-H rare earth BINOLate complex

Grace B Panetti; Jerome R Robinson; Patrick J Carroll; Michael R Gau; Brian C Manor; Patrick J Walsh; Eric J Schelter

doi:10.1039/c8dt03335h

Synthesis of novel copper-rare earth BINOLate frameworks from a hydrogen bonding DBU-H rare earth BINOLate complex

Dalton Trans. 2018 Oct 23;47(41):14408-14410. doi: 10.1039/c8dt03335h.

Authors

Grace B Panetti¹, Jerome R Robinson, Patrick J Carroll, Michael R Gau, Brian C Manor, Patrick J Walsh, Eric J Schelter

Affiliation

¹ P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, USA. pwalsh@sas.upenn.edu schelter@sas.upenn.edu.

PMID: 30183038
DOI: 10.1039/c8dt03335h

Abstract

The preparation of a novel H-bonding DBU-H+ BINOLate Rare Earth Metal complex enabled the synthesis of the first copper-Rare Earth Metal BINOLate complex (CuDBU-REMB). CuDBU-REMB was compared to the analogous Li complex using X-ray crystallography and Exchange NMR spectroscopy (EXSY). The results provide insight into the role of the secondary metal cation in the framework's stabilization.