A microporous hydrogen-bonded organic framework: exceptional stability and highly selective adsorption of gas and liquid

J Am Chem Soc. 2013 Aug 14;135(32):11684-7. doi: 10.1021/ja403002m. Epub 2013 Aug 1.

Abstract

An extremely stable hydrogen-bonded organic framework, HOF-8, was fabricated. HOF-8 is not only thermally stable but also stable in water and common organic solvents. More interestingly, desolvated HOF-8 exhibits high CO2 adsorption as well as highly selective CO2 and C6H6 adsorption at ambient temperature.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adsorption
  • Benzamides / chemistry*
  • Benzene / isolation & purification*
  • Carbon Dioxide / isolation & purification*
  • Gases / isolation & purification
  • Hydrogen Bonding
  • Models, Molecular
  • Porosity

Substances

  • Benzamides
  • Gases
  • benzene-1,3,5-tricarboxamide
  • Carbon Dioxide
  • Benzene