Adsorption of dyestuff from aqueous solutions through oxalic acid-modified swede rape straw: adsorption process and disposal methodology of depleted bioadsorbents

Bioresour Technol. 2013 Jun:138:191-7. doi: 10.1016/j.biortech.2013.03.146. Epub 2013 Mar 30.

Abstract

Swede rape straw (Brassica napus L.) was modified by oxalic acid under mild conditions producing an efficient dye adsorbent (SRSOA). This low-cost and environmental friendly bioadsorbent was characterized by various techniques and then applied to purify dye-contaminated aqueous solutions. Equilibrium study showed that the Langmuir model demonstrated the best fit to the equilibrium data and the methylene blue (MB) adsorption capacity calculated by this model was 432mgg(-1). The adsorption process and mechanism is also discussed. To properly deal with the dye-loaded bioadsorbents, the disposal methodology is discussed and a biochar based on depleted bioadsorbents was for the first time produced and examined. This method both solved the disposal problem of contaminant-loaded bioadsorbents and produced an useful adsorbent thereafter. The study indicates that SRSOA is a promising substitute for ACs in purifying dye-contaminated wastewater and that producing biochars from contaminant-loaded bioadsorbents maybe a feasible disposal method.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adsorption / drug effects
  • Biodegradation, Environmental / drug effects
  • Brassica napus / drug effects*
  • Brassica napus / metabolism
  • Charcoal / pharmacology
  • Coloring Agents / isolation & purification*
  • Kinetics
  • Methylene Blue / isolation & purification
  • Oxalic Acid / pharmacology*
  • Particle Size
  • Refuse Disposal / economics
  • Refuse Disposal / methods*
  • Solutions
  • Spectrometry, X-Ray Emission
  • Spectrophotometry, Ultraviolet
  • Spectroscopy, Fourier Transform Infrared
  • Thermodynamics
  • Time Factors
  • Waste Products / analysis*
  • Wastewater / chemistry
  • Water Pollutants, Chemical / isolation & purification*
  • Water Purification

Substances

  • Coloring Agents
  • Solutions
  • Waste Products
  • Waste Water
  • Water Pollutants, Chemical
  • biochar
  • Charcoal
  • Oxalic Acid
  • Methylene Blue