Abstract
Complex cyclic azomethine imines possessing a β-aminocarbonyl motif can be accessed readily from simple alkenes and hydrazones. This alkene aminocarbonylation approach allows formation of ketone-derived azomethine imines of unprecedented complexity. Since unsymmetrical hydrazones are used, two stereoisomers are formed: the reactivity of chiral derivatives is explored in both intra- and intermolecular systems.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alkenes / chemistry*
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Azo Compounds / chemical synthesis*
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Azo Compounds / chemistry
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Catalysis
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Combinatorial Chemistry Techniques
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Cyclization
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Hydrazones / chemistry*
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Imines / chemical synthesis*
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Imines / chemistry
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Ketones / chemical synthesis
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Ketones / chemistry
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Molecular Structure
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Stereoisomerism
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Thiosemicarbazones / chemical synthesis*
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Thiosemicarbazones / chemistry
Substances
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Alkenes
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Azo Compounds
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Hydrazones
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Imines
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Ketones
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Thiosemicarbazones
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azomethine