2-(4-Bromo-phen-yl)acetohydrazide

Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2269. doi: 10.1107/S1600536812027006. Epub 2012 Jun 30.

Abstract

In the title compound, C(8)H(9)BrN(2)O, the 1-bromo-4-methyl-benzene group and the formic hydrazide moiety [r.m.s. deviations of 0.0129 and 0.0038 Å] are oriented at a dihedral angle of 80.66 (11)°. In the crystal, mol-ecules are linked via strong N-H⋯O hydrogen bonds, leading to the formation of chains in the [010] direction. These chains are linked via weaker N-H⋯N and N-H⋯O hydrogen bonds, with R(2) (2)(7) and R(3) (2)(7) ring motifs, forming a two-dimensional network parallel to (001).