Optimization of furfural and 5-hydroxymethylfurfural production from wheat straw by a microwave-assisted process

Bioresour Technol. 2012 Apr:109:215-23. doi: 10.1016/j.biortech.2012.01.031. Epub 2012 Jan 16.

Abstract

Optimization of acid-catalyzed conversion conditions of wheat straw into furfural, 5-hydroxymethylfurfural (HMF), glucose, and xylose was studied by response surface methodology (RSM). A central composite design (CCD) was used to determine the effects of independent variables, including reaction temperature (140-200 °C), residence time (1-41 min), pH (0.1-2.1), and liquid:solid ratio (15-195 mL/g) on furan and sugar production. The surface response analysis revealed that temperature, time and pH had a strong influence on the furfural, HMF, xylose and glucose yield, whereas liquid to solid ratio was found not to be significant. The initial pH of solution was the most important variable in acid-catalyzed conversion of wheat straw to furans. The maximum predicted furfural, HMF, xylose and glucose yields were 66%, 3.4%, 100%, and 65%, respectively. This study demonstrated that the microwave-assisted process was a very effective method for the xylose production from wheat straw by diluted acid catalysis.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Analysis of Variance
  • Biotechnology / methods*
  • Catalysis
  • Furaldehyde / analogs & derivatives*
  • Furaldehyde / metabolism
  • Glucose / analysis
  • Hydrogen-Ion Concentration
  • Microwaves*
  • Models, Chemical
  • Regression Analysis
  • Temperature
  • Time Factors
  • Triticum / chemistry*
  • Waste Products / analysis*
  • Xylose / analysis

Substances

  • Waste Products
  • 5-hydroxymethylfurfural
  • Xylose
  • Furaldehyde
  • Glucose