Scaling of dynamics with the range of interaction in short-range attractive colloids

Phys Rev Lett. 2005 Feb 25;94(7):078301. doi: 10.1103/PhysRevLett.94.078301. Epub 2005 Feb 23.

Abstract

We numerically study the dependence of the dynamics on the range of interaction Delta for the short-range square well potential. We find that, for small Delta, dynamics scale exactly in the same way as thermodynamics, both for Newtonian and Brownian microscopic dynamics. For interaction ranges from a few percent down to the Baxter limit, the relative location of the attractive-glass line and the liquid-gas line does not depend on Delta. This proves that, in this class of potentials, disordered arrested states (gels) can be generated only as a result of a kinetically arrested phase separation.