Network morphology of straight and polymer modified asphalt cements

Microsc Res Tech. 1997 Sep 1;38(5):529-43. doi: 10.1002/(SICI)1097-0029(19970901)38:5<529::AID-JEMT11>3.0.CO;2-O.

Abstract

Asphalt cements are often regarded as a colloidal system containing several hydrocarbon constituents: asphaltenes, resins, and oils. The high molecular weight asphaltene particles are considered to be covered in a sheath of resins and dispersed in the lower molecular weight oily medium [Whiteoak (1990) The Shell Bitumen Handbook (Shell Bitumen UK, Riversdell House, Surrey, UK)]. However, the exact arrangement of the asphaltene particles within the oily phase will vary depending on the relative amounts of resin, asphaltene, and oils. It is this arrangement and the degree of association between asphaltene particles that govern the rheological properties of the cement [Simpson et al. (1961) J. Chem. Eng. Data 6:426-429; Whiteoak (1990)]. Here we report for the first time the observation of a three-dimensional network of asphaltene strands within straight, polymer-modified, and aged asphalt cements. While the existence of a asphaltene/resin micelle network has been proposed in previous studies [Whiteoak (1990)], direct observation has not been reported. The network is expected to greatly influence the rheological properties of the asphalt binder and ultimately the properties of asphalt concretes. In situ fracture studies of asphalt cement/aggregate composites indicate a possible correlation between the network structure and adhesion between the cement binder and aggregate.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Hydrocarbons / analysis*
  • Hydrocarbons / chemistry*
  • Microscopy, Electron, Scanning
  • Polymers

Substances

  • Hydrocarbons
  • Polymers
  • asphalt