Magnetic biochar enhanced copper immobilization in agricultural lands: Insights from adsorption precipitation and redox

Biochar has exceeded expectations for heavy metal immobilization and has been prepared from widely available sources and inexpensive materials. In this research, coconut shell biochar (CSB), bamboo biochar (BC), magnetic coconut shell charcoal (MCSB), and magnetic bamboo biochar (MBC) were manufactured via co-pyrolysis, and their adsorption properties were tested. The pseudo-secondary (R² = 0.980-0.985) adsorption kinetic fittings for the four biochas were superior to the pseudo-primary kinetics (R² = 0.969-0.982). Unmodified biochar adsorption isotherms were more consistent with the Freundlich model, while magnetic biochar fitted Langmuir models better. The maximum adsorption capacity of MCSB for Cu(Ⅱ) reached 371.50 mg g^-1. The adsorption mechanisms quantitatively analysis of the biochar indicated that chemical precipitation and ion exchange contributed to the adsorption, in which the magnetic biochar metal-π complexation also enhanced the adsorption. The pot experiment revealed that MCSB (2.0 %DW) significantly enhanced the biomass of lettuce, and facilitated the immobilization of DTPA-Cu (p < 0.05). SEM-EDS, XPS, and FTIR were utilized for morphological characterization and functional group identification, and the increased active adsorption sites (-OH, -COOH, CO, and Fe-O) of MCSB enhanced chemisorption and π-π EDA complexation with Cu(Ⅱ). EEM-PARAFAC and RDA analysis further elucidated that magnetic biochar immobilized copper and reduced biotoxicity (efficiency: 76.12%) by adjusting soil pH, phosphate, and SOM release (negative correlation). The presence of iron oxides (FeO_x) promoted in situ adsorption of metallic copper and offered new insights into soil remediation.