3D printed denture base material: The effect of incorporating TiO2 nanoparticles and artificial ageing on the physical and mechanical properties

Ahmed Altarazi; Julfikar Haider; Abdulaziz Alhotan; Nick Silikas; Hugh Devlin

doi:10.1016/j.dental.2023.10.005

3D printed denture base material: The effect of incorporating TiO₂ nanoparticles and artificial ageing on the physical and mechanical properties

Dent Mater. 2023 Dec;39(12):1122-1136. doi: 10.1016/j.dental.2023.10.005. Epub 2023 Oct 13.

Authors

Ahmed Altarazi¹, Julfikar Haider², Abdulaziz Alhotan³, Nick Silikas⁴, Hugh Devlin⁵

Affiliations

¹ Division of Dentistry, School of Medical Sciences, University of Manchester, Manchester M13 9PL, United Kingdom; Restorative Dental Science, College of Dentistry, Taibah University, Saudi Arabia. Electronic address: atarazi@taibahu.edu.sa.
² Division of Dentistry, School of Medical Sciences, University of Manchester, Manchester M13 9PL, United Kingdom; Department of Engineering, Manchester Metropolitan University, Manchester, United Kingdom.
³ Dental Health Department, College of Applied Medical Sciences, King Saud University, Riyadh, Saudi Arabia.
⁴ Division of Dentistry, School of Medical Sciences, University of Manchester, Manchester M13 9PL, United Kingdom. Electronic address: Nikolaos.silikas@manchester.ac.uk.
⁵ Division of Dentistry, School of Medical Sciences, University of Manchester, Manchester M13 9PL, United Kingdom.

PMID: 37839997
DOI: 10.1016/j.dental.2023.10.005

Abstract

Objectives: To evaluate the physical and mechanical properties of three-dimensional (3D) printed denture base resin incorporating TiO2 nanoparticles (NPs), subjected to a physical ageing process.

Methods: Acrylic denture base samples were prepared by a Stereolithography (SLA) 3D printing technique reinforced with different concentrations (0.10, 0.25, 0.50, and 0.75) of silanated TiO₂ NPs. The resulting nanocomposite materials were characterized in terms of degree of conversion (DC), and sorption/solubility flexural strength, impact strength, Vickers hardness and Martens hardness and compared with unmodified resin and conventional heat-cured (HC) material. The nanocomposites were reassessed after subjecting them to ageing in artificial saliva. A fractured surface was studied under a scanning electron microscope (SEM).

Results: The addition of TiO₂ NPs into 3D-printed resin significantly improved flexural strength/modulus, impact strength, Vickers hardness, and DC, while also slightly enhancing Martens hardness compared to the unmodified resin. Sorption values did not show any improvements, while solubility was reduced significantly. The addition of 0.10 wt% NPs provided the highest performance amongst the other concentrations, and 0.75 wt% NPs showed the lowest. Although ageing degraded the materials' performance to a certain extent, the trends remained the same. SEM images showed a homogenous distribution of the NPs at lower concentrations (0.10 and 0.25 wt%) but revealed agglomeration of the NPs with the higher concentrations (0.50 and 0.75 wt%).

Significance: The outcomes of this study suggested that the incorporation of TiO₂ NPs (0.10 wt%) into 3D-printed denture base material showed superior performance compared to the unmodified 3D-printed resin even after ageing in artificial saliva. The nanocomposite has the potential to extend service life of denture bases in future clinical use.

Keywords: 3D printed resin; Additive manufacturing; Denture base; Martens hardness; Nanocomposite, Stereolithography (SLA); Nanoparticles; Titanium dioxide.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Denture Bases*
Materials Testing
Nanoparticles*
Printing, Three-Dimensional
Saliva, Artificial
Surface Properties

Substances

titanium dioxide
Saliva, Artificial