A novel DBD/VUV/PMS process for efficient sulfadiazine degradation in wastewater: Singlet oxygen-dominated nonradical oxidation

In this study, a novel process of dielectric barrier discharge plasma/vacuum ultraviolet/peroxymonosulfate (DBD/VUV/PMS) for the nonradical-dominated degradation of sulfadiazine (SDZ) was investigated. The hybrid system has significant synergistic effects, with 95.5% SDZ and 68.3% TOC removal within 10 min. The activation efficiency of DBD/VUV (69.0%) on PMS via multipath was 2.07 times higher than that of single DBD (33.3%) under alkaline conditions. Electron paramagnetic resonance analyses and trapping experiments showed ¹O₂ was the primary active substance in the DBD/VUV/PMS process. The predominant role of ¹O₂ revealed that SDZ removal mainly followed the nonradical reaction pathway, contrary to the previously reported non-thermal plasma (NTP)-based radical-dominated process. Multiple spectroscopy analysis showed the efficient degradation process of SDZ. Unlike the radical attack sites, the SDZ transformation pathway by nonradical ¹O₂ was probably initiated by an aniline ring site attack based on density functional theory (DFT) calculations and product analyses. The DBD/VUV/PMS process reduced energy consumption by 69% compared to DBD. Finally, the evaluation of ecotoxicity and PMS utilization demonstrated the advantages and application prospects of the DBD/VUV/PMS process. This research developed a new nonradical-dominated pathway for antibiotic degradation by the photo/plasma/persulfate process.