Lewis Acid Probe for Basicity of Sulfide Electrolytes Investigated by 11B Solid-State NMR

Shi-Kai Jiang; Sheng-Chiang Yang; Yosef Nikodimos; Shing-Jong Huang; Kuan-Yu Lin; Yi-Hui Kuo; Bo-Yang Tsai; Jhao-Nan Li; Shawn D Lin; Jyh-Chiang Jiang; She-Huang Wu; Wei-Nien Su; Bing Joe Hwang

doi:10.1021/jacsau.3c00242

Lewis Acid Probe for Basicity of Sulfide Electrolytes Investigated by ¹¹B Solid-State NMR

JACS Au. 2023 Aug 4;3(8):2174-2182. doi: 10.1021/jacsau.3c00242. eCollection 2023 Aug 28.

Authors

Affiliations

¹ Department of Chemical Engineering, National Taiwan University of Science and Technology, Taipei 106335, Taiwan.
² Department of Chemistry, National Taiwan University, Taipei 10617, Taiwan.
³ Graduate Institute of Applied Science and Technology, National Taiwan University of Science and Technology, Taipei 106335, Taiwan.
⁴ National Synchrotron Radiation Research Center (NSRRC), Hsinchu 30076, Taiwan.
⁵ Sustainable Electrochemical Energy Development Center, National Taiwan University of Science and Technology, Taipei 106335, Taiwan.

Abstract

Sulfide-based solid-state lithium-ion batteries (SSLIB) have attracted a lot of interest globally in the past few years for their high safety and high energy density over the traditional lithium-ion batteries. However, sulfide electrolytes (SEs) are moisture-sensitive which pose significant challenges in the material preparation and cell manufacturing. To the best of our knowledge, there is no tool available to probe the types and the strength of the basic sites in sulfide electrolytes, which is crucial for understanding the moisture stability of sulfide electrolytes. Herein, we propose a new spectral probe with the Lewis base indicator BBr₃ to probe the strength of Lewis basic sites on various sulfide electrolytes by ¹¹B solid-state NMR spectroscopy (¹¹B-NMR). The active sulfur sites and the corresponding strength of the sulfide electrolytes are successfully evaluated by the proposed Lewis base probe. The probed strength of the active sulfur sites of a sulfide electrolyte is consistent with the results of DFT (density functional theory) calculation and correlated with the H₂S generation rate when the electrolyte was exposed in moisture atmosphere. This work paves a new way to investigate the basicity and moisture stability of the sulfide electrolytes.