Green construction of metal- and additive-free citrus peel-derived carbon dot/g-C₃N₄ photocatalysts for the high-performance photocatalytic decomposition of sunset yellow

In this study, novel, metal-free, CP-derived CDs/g-C₃N₄ nanocomposites (CDCNs) were created by introducing citrus peel-derived carbon dots (CP-derived CDs) into graphite carbon nitride (g-C₃N₄) by a green hydrothermal method. The CDCNs were revealed to have superior photoelectrochemical properties relative to pristine g-C₃N₄ for the photocatalytic degradation of the food dye sunset yellow (SY) under visible light. For SY decomposition, the recommended catalyst contributed almost 96.3% to the photodegradation rate after 60 min of irradiation, showing satisfactory reusability, structural stability and biocompatibility. Moreover, a mechanism for enhanced photocatalytic SY degradation was proposed according to band analysis, free radical trapping and electron paramagnetic resonance (EPR) results. A possible pathway for SY photodegradation was also predicted from UV-visible (UV-Vis) spectroscopy and high-performance liquid chromatography (HPLC) results. The constructed nonmetallic nanophotocatalysts afford a novel route for the elimination of harmful dyes and for the resource conversion of citrus peels.