Preparation of the alginate/carrageenan/shellac films reinforced with cellulose nanocrystals obtained from enteromorpha for food packaging

Enteromorpha prolifera belonging to the chlorophyta phylum is the main pollutant of "green tide", and propagates rapidly in recent years. However, there is almost no high-value enteromorpha treatment method at present. This study aimed to extract cellulose nanocrystals (CNC) from enteromorpha and prepare the CNC reinforced films based on alginate, carrageenan and shellac for food packaging. The effects of alginate, κ-carrageenan, cellulose nanocrystals and glycerin on the CNC reinforced alginate/carrageenan films (AC films) properties were studied systematically in this work. The results showed that the mechanical properties, swelling properties, and barrier properties of the AC could be adjusted by the concentrations of the different components. In addition, response surface methodology (RSM) was used to optimize the formula of the AC used for food packaging according to the requirements of the practical application. Furthermore, in order to further improve the food packaging capacity of the composite films, shellac was added to the optimized alginate/carrageenan films (OAC films) to obtain the shellac optimized alginate/carrageenan films (SOAC films). Finally, the OAC films and SOAC films showed excellent properties to extend the storage time of chicken breast and cherry tomatoes in the food storage experiment.