Beating signals in CdSe quantum dots measured by low-temperature 2D spectroscopy

J Chem Phys. 2022 Jul 7;157(1):014201. doi: 10.1063/5.0089798.

Abstract

Advances in ultrafast spectroscopy can provide access to dynamics involving nontrivial quantum correlations and their evolutions. In coherent 2D spectroscopy, the oscillatory time dependence of a signal is a signature of such quantum dynamics. Here, we study such beating signals in electronic coherent 2D spectroscopy of CdSe quantum dots (CdSe QDs) at 77 K. The beating signals are analyzed in terms of their positive and negative Fourier components. We conclude that the beatings originate from coherent LO-phonons of CdSe QDs. No evidence for the QD size dependence of the LO-phonon frequency was identified.

MeSH terms

  • Cadmium Compounds* / chemistry
  • Quantum Dots* / chemistry
  • Selenium Compounds* / chemistry
  • Spectrum Analysis
  • Temperature

Substances

  • Cadmium Compounds
  • Selenium Compounds