Confining MoSe₂ Nanosheets into N-Doped Hollow Porous Carbon Microspheres for Fast-Charged and Long-Life Potassium-Ion Storage

The potassium-ion battery (PIB) is the most promising alternative to a lithium-ion battery (LIB). Exploitation of a suitable electrode material is crucial to promote the development of PIBs. The MoSe₂ material has attracted much attention due to its high theoretical capacity, unique layered structure, and good conductivity. However, the potassium storage property of MoSe₂ has been suffering from structural fragmentation and sluggish reaction kinetic caused by large potassium ions upon insertion/extraction, which needs to be further improved. Herein, the MoSe₂ nanosheets are confined into N-doped hollow porous carbon microspheres (MoSe₂@N-HCS) by spray drying and high-temperature selenization. It delivers a superior rate performance of 113.7 mAh g^-1 at 10 A g^-1 and remains at a high capacity of 158.3 mAh g^-1 at 2 A g^-1 even after 16 700 cycles for PIBs. The excellent electrochemical performance can be attributed to unique structure, N-doping, and robust chemical bonds. The storage mechanism of MoSe₂ for potassium ions was explored. The outstanding properties of MoSe₂@N-HCS make it a promising anode material for PIBs.