Enhanced CO₂ Photocatalysis by Indium Oxide Hydroxide Supported on TiN@TiO₂ Nanotubes

Herein is developed a ternary heterostructured catalyst, based on a periodic array of 1D TiN nanotubes, with a TiO₂ nanoparticulate intermediate layer and a In₂O_3-x(OH)_y nanoparticulate shell for improved performance in the photocatalytic reverse water gas shift reaction. It is demonstrated that the ordering of the three components in the heterostructure sensitively determine its activity in CO₂ photocatalysis. Specifically, TiN nanotubes not only provide a photothermal driving force for the photocatalytic reaction, owing to their strong optical absorption properties, but they also serve as a crucial scaffold for minimizing the required quantity of In₂O_3-x(OH)_y nanoparticles, leading to an enhanced CO production rate. Simultaneously, the TiO₂ nanoparticle layer supplies photogenerated electrons and holes that are transferred to active sites on In₂O_3-x(OH)_y nanoparticles and participate in the reactions occurring at the catalyst surface.