In recent days the nanomagnetic biocomposites have been evolved as sustainable green catalysts. In that context, we are prompted to design and synthesize a novel Pd NP adorned chitosan-starch dual biopolymer encapsulated core-shell type magnetic nanocomposite (Fe3O4@CS-Starch/Pd) in an eco-friendly pathway applying ultrasound irradiations. The morphological and physicochemical features of the material were determined using several advanced techniques like FT-IR, FESEM, HRTEM, EDX, atomic mapping, VSM, XRD and ICP-OES. Catalytic efficiency of the material was investigated in the ultrasound assisted classical Suzuki-Miyaura coupling towards the synthesis of diverse range of biaryl derivatives and in the catalytic reduction of 4-Nitrophenol.In both the protocols the catalyst exhibited excellent performances. Sonication had a significant role in enhancing the catalytic performances in both the reactions as compared to conventional heating. Due to super-paramagnetism, the catalyst was easily magnetically isolable and reused in 11 cycles without considerable leaching and change in reactivity.
Keywords: Pd NP; Reduction; Suzuki coupling.
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