Nano-manganese oxides-modified biochar for efficient chelated copper citrate removal from water by oxidation-assisted adsorption process

Removal of chelated copper from wastewater is more difficult than that of copper ions owing to its stable structure, wide range of pH tolerance, and stronger mobility. Copper citrate (CuCA) widely exists in the water system and inevitably poses serious hazards to human health and environment. Biochar as economic functional material has been widely used for environmental applications, especially in wastewater treatment. This study focused on the performance of manganese oxide-modified biochar (BC-MnO_x) toward uptake and removal of CuCA and to understand the related mechanism. The result indicated that the CuCA removal efficiency reached up to 99%. High removal efficiency and low concentration of dissolved Mn over a wide pH range proved that the BC-MnO_x is efficient and chemically stable. Furthermore, the removal mechanism may involve the following processes: First, CuCA was removed via the chemical bonds formed between CuCA and MnO_x on the surface of BC. Second, chemisorption due to the oxygen-containing functional groups or physisorption of porous structure in BC worked synergistically on CuCA. Third, CuCA was partially oxidized into low molecular weight acids by means of MnO_x, while the released Cu ions were retained on the adsorbent surface. This study demonstrates that BC-MnO_x is a promising material for the removal of CuCA from wastewater.