Hydrogels as an Emerging Material Platform for Solar Water Purification

Acc Chem Res. 2019 Nov 19;52(11):3244-3253. doi: 10.1021/acs.accounts.9b00455. Epub 2019 Oct 21.

Abstract

Growing concern over water scarcity leads to increased research interest in advanced water purification technologies. Solar water purification, which uses solar energy to separate water and impurities through vaporization, enables the utilization of sustainable energy and potential freshwater resources to alleviate water scarcity. However, the essential process of solar water evaporation to remove impurities is energy intensive. Insufficient solar absorption and thermal loss limited the vapor generation rate and, thus, lowered the purified water yield. Diffuse natural sunlight cannot satisfy the intrinsic energy demand for rapid water vaporization. Therefore, developing new material platforms that can simultaneously provide high solar absorption, effective energy utilization, and low energy demand for water vaporization to achieve highly efficient solar water purification under natural sunlight is anticipated. In this Account, we review our recent progress on hydrogel-based evaporators for solar water purification in terms of material selection, molecular engineering, and structural design. First, we introduce the unique water state in hydrogels consisting of free, intermediate, and bound water, of which intermediate water has a reduced energy demand for water evaporation. Then, we describe the design principles of hydrogel-based solar evaporators, where the polymeric networks are tailored to regulate the water state. The water state in hydrogels defines the vaporization behavior of water. Thus, the polymer networks of hydrogels can be architected to tune the water state and, hence, to further reduce the evaporation enthalpy of water. Armed with fundamental gelation chemistry, we discuss synthetic strategies of hydrogels for efficient vapor generation. By incorporating solar absorbers with hydrophilic polymer networks, solar energy is harvested and converted to heat energy, which can be in situ utilized to power the vaporization of contained water in the molecular meshes, and the solar absorbers having strong interaction with hydrogels guide the formation of microstructure to reduce the energy loss and ensure adequate water transport of evaporative water. Regulating the vaporizing fronts, engineering the surface of hydrogels has been focused to favor the evaporationof water to further enhance the solar-to-vapor efficiency. By using hydrophilic polymers as building blocks, the hydrogel-based solar evaporators have also been endowed with multiple functionalities, such as antifouling, permselectivity, and thermal responsiveness, to improve water collection and purification abilities. Taking advantages of these merits, hydrogels have emerged as a promising materials platform to enable efficient solar water purification under natural sunlight. This Account serves to promote future efforts toward practical purification systems using hydrogel-based solar evaporators to mitigate water scarcity by improving their performance, scalability, stability, and sustainability.

Publication types

  • Research Support, Non-U.S. Gov't