Synthesis and Phase Transformation Studies of Dysprosium-Doped Bi4V2O11 Nanoparticles and Their Application in Visible Light Photocatalytic Degradation of Tetracycline Drug

Faria K Naqvi; Mohd Faraz; Saba Beg; Neeraj Khare

doi:10.1021/acsomega.8b01012

Synthesis and Phase Transformation Studies of Dysprosium-Doped Bi₄V₂O₁₁ Nanoparticles and Their Application in Visible Light Photocatalytic Degradation of Tetracycline Drug

ACS Omega. 2018 Sep 30;3(9):11300-11306. doi: 10.1021/acsomega.8b01012. Epub 2018 Sep 17.

Authors

Faria K Naqvi¹, Mohd Faraz², Saba Beg¹, Neeraj Khare²

Affiliations

¹ Department of Chemistry, Aligarh Muslim University, Aligarh 202002, India.
² Department of Physic, Indian Institute of Technology Delhi, Delhi 110016, India.

Abstract

Recently, Bi₄V₂O₁₁ as an electrolyte material has pulled in considerable consideration because of its remarkable novel applications. In this article, novel, dysprosium-doped (x = 0.2, 0.3, 0.4, and 0.5) Bi₄V₂O₁₁ (Dy/BVO) nanoparticles have been synthesized by sol-gel strategy. The photocatalyst Dy/BVO nanoparticles exhibit higher photocatalytic efficiency than BVO nanoparticles assessed by debasement of tetracycline drug under visible light illumination. Our work focuses on the phase transformation, conducting properties, and mechanisms of the Dy/BVO nanoparticles in relation to execute some methods of processing and manufacturing product in commercial applications. The characterization of Dy/BVO was performed by Fourier transform infrared, X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray analysis, and UV-vis analysis. ac impedance spectroscopy was used to analyze the conducting behavior of synthesized nanoparticles in the temperature range 100-600 °C. The photocatalytic activity revealed that Dy/BVO remarkably enhanced the photocatalytic activity. This is the first report that Dy/BVO can destroy the drug effluent which is coming from the drug industry and also worried about the human health hazards.