Seawater-Assisted Self-Healing of Catechol Polymers via Hydrogen Bonding and Coordination Interactions

ACS Appl Mater Interfaces. 2016 Jul 27;8(29):19047-53. doi: 10.1021/acsami.6b04075. Epub 2016 Jul 12.

Abstract

It is highly desirable to prevent crack formation in polymeric materials at an early stage and to extend their lifespan, particularly when repairs to these materials would be difficult for humans. Here, we designed and synthesized catechol-functionalized polymers that can self-heal in seawater through hydrogen bonding and coordination. These bioinspired acrylate polymers are originally viscous materials, but after coordination with environmentally safe, common metal cations in seawater, namely, Ca(2+) and Mg(2+), the mechanical properties of the polymers were greatly enhanced from viscous to tough, hard materials. Reduced swelling in seawater compared with deionized water owing to the higher osmotic pressure resulted in greater toughness (∼5 MPa) and self-healing efficiencies (∼80%).

Keywords: bioinspired polymers; catechol; metallopolymers; seawater; self-healing.