Luminescence and energy transfer of the color-tunable phosphor Li₆Gd(BO₃)₃:Tb³⁺/Bi³⁺, Eu³⁺

Appl Radiat Isot. 2016 Feb:108:148-153. doi: 10.1016/j.apradiso.2015.12.042. Epub 2015 Dec 17.

Abstract

Bi(3+)/Tb(3+), Eu(3+) co-doped Li6Gd(BO3)3 (LGBO) phosphors were synthesized via a traditional solid-state method. Phase purity was investigated using X-ray diffraction, absorption strength of the phosphors were investigated by UV-vis absorption spectra, and the photoluminescence properties of the phosphors were studied systematically. Results showed that the emission intensity of Bi(3+), Eu(3+) co-doped LBOG was 2.76 times higher than that of Eu(3+)-doped LGBO irradiated at 275 nm, thereby implying the possibility of energy transfer from Bi(3+) to Eu(3+). The excitation spectra of Tb(3+), Eu(3+) co-doped LGBO phosphors are broader in comparison with single-doped phosphors and show tunable colors from green to yellow to orange-red when the ratio of Tb(3+) to Eu(3+) is adjusted These results demonstrate that LGBO:Tb(3+), Eu(3+) phosphors have potential use in light-emitting diodes.

Keywords: Luminescence; Optical properties; Phosphor.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Color*
  • Colorimetry / methods
  • Dose-Response Relationship, Radiation
  • Energy Transfer / radiation effects*
  • Lanthanoid Series Elements / chemistry*
  • Lighting / methods*
  • Luminescent Measurements / methods*
  • Materials Testing
  • Radiation Dosage

Substances

  • Lanthanoid Series Elements