Co5In(BTC)4[B2O4(OH)]2: the first MOF material constructed by borate polyanions and carboxylate mixed ligands

Sa-Ying Li; Zhi-Hong Liu

doi:10.1039/c5dt03535j

Co5In(BTC)4[B2O4(OH)]2: the first MOF material constructed by borate polyanions and carboxylate mixed ligands

Dalton Trans. 2016 Jan 7;45(1):66-9. doi: 10.1039/c5dt03535j.

Authors

Sa-Ying Li¹, Zhi-Hong Liu²

Affiliations

¹ Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710062, P. R. China and Department of Chemistry and Chemical Engineering, Shaanxi Xueqian Normal University, Xi'an 710061, P. R. China. liuzh@snnu.edu.cn.
² Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710062, P. R. China.

PMID: 26606895
DOI: 10.1039/c5dt03535j

Abstract

A novel heterometallic organic-inorganic hybrid MOF material, Co5In(BTC)4[B2O4(OH)]2, has been synthesized under ionothermal conditions. Its structure is characterized as a 3D open framework constructed by the Co2.5In0.5[B2O4(OH)] cluster and the 1,3,5-benzenetricarboxylate ligand. Furthermore, its fluorescent and adsorption properties have also been studied.

Publication types

Research Support, Non-U.S. Gov't