adj-Dicarbachlorin, the first free base carbaporphyrinoid system with an internal methylene unit

Chem Commun (Camb). 2015 Nov 14;51(88):15952-5. doi: 10.1039/c5cc06890h. Epub 2015 Sep 17.

Abstract

Base-catalyzed condensation of dicyclopentadienylmethane with a dipyrrylmethane dialdehyde gave a dicarbachlorin with an internal CH2 group. This unusual porphyrinoid retained highly diatropic characteristics and exhibited a porphyrin-like UV-vis spectrum.