pH controlled Ho³⁺-Yb³⁺ codoped Y₂O₃ nanowires for display devices

Spectrochim Acta A Mol Biomol Spectrosc. 2015:151:213-7. doi: 10.1016/j.saa.2015.06.047. Epub 2015 Jun 20.

Abstract

The wire like structure with particle size in the nanometer range of Ho(3+)-Yb(3+) codoped Y2O3 phosphors have been synthesized through hydrothermal synthesis route by controlling the pH value. The Field emission scanning electron microscopy (FESEM) and X-ray diffraction (XRD) analysis of the synthesized phosphor powders have been studied which confirms the formation of nanowires in the prepared materials and the formation of proper crystalline structure respectively. The frequency upconversion emission spectra under 980 nm excitation have been recorded and an efficient green emission has been observed. The excitation energy corresponding to the NIR photon seems to be fully utilized for the emission lying in the green region. The Fourier transform infrared (FTIR) spectroscopic analysis for existence of the impurities in the developed material has also been performed. The experimental observation proves the utility of the prepared material in the display devices and diagnosis purposes.

Keywords: Electron microscopy; Luminescence; Optical materials; X-ray diffraction.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Holmium / chemistry*
  • Hydrogen-Ion Concentration
  • Luminescent Agents / chemistry*
  • Luminescent Measurements
  • Microscopy, Electron, Scanning / instrumentation*
  • Nanowires / chemistry*
  • Spectroscopy, Fourier Transform Infrared / instrumentation
  • X-Ray Diffraction / instrumentation*
  • Ytterbium / chemistry*
  • Yttrium / chemistry*

Substances

  • Luminescent Agents
  • Yttrium
  • Ytterbium
  • Holmium
  • yttria