Manganese(III)-mediated alkenyl C(sp2)-P bond formation from the reaction of β-nitrostyrenes with dialkyl phosphites

Jian-Fei Xue; Shao-Fang Zhou; Ye-Ye Liu; Xiangqiang Pan; Jian-Ping Zou; Olayinka Taiwo Asekun

doi:10.1039/c5ob00404g

Manganese(III)-mediated alkenyl C(sp2)-P bond formation from the reaction of β-nitrostyrenes with dialkyl phosphites

Org Biomol Chem. 2015 May 7;13(17):4896-902. doi: 10.1039/c5ob00404g.

Authors

Jian-Fei Xue¹, Shao-Fang Zhou, Ye-Ye Liu, Xiangqiang Pan, Jian-Ping Zou, Olayinka Taiwo Asekun

Affiliation

¹ Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Soochow University, 199 Renai Street, Suzhou, Jiangsu 215123, China. jpzou@suda.edu.cn panxq@suda.edu.cn.

PMID: 25812140
DOI: 10.1039/c5ob00404g

Abstract

Mn(OAc)3-mediated tandem phosphonyl radical addition to β-nitrostyrenes followed by denitration to form (E)-2-alkenyl phosphonates in good yield is described.