Dye-sensitized solar cell based on spray deposited ZnO thin film: performance analysis through DFT approach

Spectrochim Acta A Mol Biomol Spectrosc. 2015 Feb 5:136 Pt B:986-92. doi: 10.1016/j.saa.2014.09.121. Epub 2014 Oct 5.

Abstract

A dye-sensitized solar cell based on a spray deposited zinc oxide (ZnO) photoanode with Evans blue as a sensitizer was fabricated. Structural analysis confirms the hexagonal wurtzite phase of the ZnO photoanode with c-axis orientation. Surface morphology of the ZnO photoanode shows uniform distribution of spherically-shaped grains, ranging from 18 nm to 25 nm. The power conversion efficiency of the device was measured as 0.1%. Density functional theory was adopted to study the observed photovoltaic performance of the fabricated device. The analysis of the electronic properties of Evans blue dye showed that it has a pronounced effect on the observed device performance.

Keywords: Density functional theory; Density of states; Dye sensitized solar cell; Evans blue; ZnO.

MeSH terms

  • Coloring Agents / chemistry*
  • Electrodes
  • Electrons
  • Evans Blue / chemistry
  • Microscopy, Electron, Scanning
  • Models, Molecular*
  • Molecular Conformation
  • Optical Phenomena
  • Quantum Theory*
  • Solar Energy*
  • Spectrophotometry, Ultraviolet
  • Spectroscopy, Fourier Transform Infrared
  • Vibration
  • X-Ray Diffraction
  • Zinc Oxide / chemistry*

Substances

  • Coloring Agents
  • Evans Blue
  • Zinc Oxide