A proposed method to reconstruct the three-dimensional dispersion profile of polymeric fibres based on variable wavelength interferometry

J Microsc. 2015 Feb;257(2):123-32. doi: 10.1111/jmi.12191. Epub 2014 Oct 29.

Abstract

In this paper, we suggest a modification to the conventional variable wavelength interferometry. This modification allowed us to calculate the dispersion curve of each point inside polymeric fibres instead of calculating the mean dispersion of these fibres. This modified mathematical treatment was used to calculate the three-dimensional dispersion profile of isotactic polypropylene fibres suffering from necking deformation. The different steps of calculating the three-dimensional dispersion profile of the fibre were demonstrated. The application of this modified method revealed the variation of the fibre material dispersion before, inside and after the necking region. In addition, the birefringence profile of the necked isotactic polypropylene was determined using the proposed mathematical treatment. This allowed us to diagnose the interaction of the incident waves with necked polypropylene fibres, which gives extensive information on the orientation of the molecular chains during the formation of the necking phenomenon.

Keywords: Dispersion; fibres; polymers.