Format

Send to:

Choose Destination
See comment in PubMed Commons below
Org Biomol Chem. 2014 Oct 14;12(38):7486-8. doi: 10.1039/c4ob01633e.

Oxidative cleavage of benzylic C-N bonds under metal-free conditions.

Author information

  • 1Department of Chemistry, Zhejiang Sci-Tech University, Xiasha Campus, Hangzhou, Zhejiang Province 310018, People's Republic of China. xiao-feng.wu@catalysis.de.

Abstract

An interesting procedure for the oxidative cleavage of benzylic C-N bonds has been developed. Using TBAI as the catalyst and H2O2 as the oxidant, various benzylamines were transformed into their corresponding aromatic aldehydes in moderate to good yields. Notably, this is the first example of an oxidative cleavage of benzylic C-N bonds under metal-free conditions.

PMID:
25156588
[PubMed - in process]
PubMed Commons home

PubMed Commons

0 comments
How to join PubMed Commons

    Supplemental Content

    Full text links

    Icon for Royal Society of Chemistry
    Loading ...
    Write to the Help Desk