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Chem Commun (Camb). 2014 Aug 7;50(61):8320-3. doi: 10.1039/c4cc03478c.

A combination of the "pillaring" strategy and chiral induction: an approach to prepare homochiral three-dimensional coordination polymers from achiral precursors.

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  • 1State key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China. wxt@fjirsm.ac.cn.


Utilizing enantiopure camphorsulfonic acid as a chiral induction agent, 3D homochiral complexes were obtained from achiral 2D layers and MoO4(2-) pillars. This methodology combines the "pillaring" strategy with chiral induction, providing a new way to synthesize homochiral 3D coordination polymers intentionally from achiral precursors.

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