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Spectrochim Acta A Mol Biomol Spectrosc. 2014 Nov 11;132:733-42. doi: 10.1016/j.saa.2014.04.185. Epub 2014 May 23.

Microwave assisted synthesis, characterization and biocidal activities of some new chelates of carbazole derived Schiff bases of cadmium and tin metals.

Author information

  • 1Department of Chemistry, Banasthali University, Banasthali, Rajasthan 304022, India.
  • 2Department of Chemistry, Zakir Husain College, University of Delhi, J.L. Nehru Marg, New Delhi 110002, India.
  • 3Department of Chemistry, Banasthali University, Banasthali, Rajasthan 304022, India. Electronic address: dsbchoudhary2002@gmail.com.

Abstract

This study is planned to report the advancement of green microwave approach in the fabrication of a new series of biologically potent (N^X, where X=O/S) donor Schiff bases and their cadmium(II) and tin(II) complexes. The ligands and their metal complexes have been characterized in terms of elemental analysis, molar ionic conductance, magnetic moment and spectral (IR, UV-Vis, NMR ((1)H, (119)Sn), FAB-mass, thermal and XRD) data. The data revealed that the ligands coordinated to the metal center via nitrogen and oxygen/sulfur atoms and form an octahedral arrangement of the ligands around central metal atom. All compounds were evaluated for their in vitro antimicrobial activities against two pathogenic bacteria Bacillus subtilis and Escherichia coli and two fungi Aspergillus niger and Aspergillus flavus by standard disc diffusion method. The discs were stored in an incubator at 37°C. The compounds were dissolved in DMF at 500 and 1000 ppm concentrations for screening biocidal activity. The compounds were dissolved in DMF to get the 100 and 200 ppm concentration of test solutions for screening fungicidal activity. The inhibition zone around each disc was measured (in mm) after 24 h and 96 h for biocidal and fungicidal activities respectively.

Copyright © 2014 Elsevier B.V. All rights reserved.

KEYWORDS:

Antimicrobial activities; Carbazole; Cd(II) and Sn(II) complexes; Schiff bases; Spectral characterization

PMID:
24929756
[PubMed - indexed for MEDLINE]
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