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Org Biomol Chem. 2014 Jul 28;12(28):5227-34. doi: 10.1039/c4ob00709c. Epub 2014 Jun 11.

A survey of enoldiazo nucleophilicity in selective C-C bond forming reactions for the synthesis of natural product-like frameworks.

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  • 1Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, USA.


A survey of in situ, catalytically generated carbocations for coupling with enoldiazoacetate nucleophiles was performed. These couplings facilitate the rapid assembly of complex organodiazo compounds that provide a template for the synthesis of a variety of carbocyclic and heterocyclic ring systems.

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