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Macromol Rapid Commun. 2014 Aug;35(15):1367-71. doi: 10.1002/marc.201400167. Epub 2014 May 23.

Poly(exTTF): a novel redox-active polymer as active material for li-organic batteries.

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  • 1Laboratory of Organic and Macromolecular Chemistry, Friedrich Schiller University Jena, Humboldtstr. 10, 07743, Jena, Germany; Jena Center for Soft Matter (JCSM), Friedrich Schiller University Jena, Philosophenweg 7, 07743, Jena, Germany.


The first polymer bearing exTTF units intended for the use in electrical charge storage is presented. The polymer undergoes a redox reaction involving two electrons at -0.20 V vs Fc/Fc(+) and is applied as active cathode material in a Li-organic battery. The received coin cells feature a theoretical capacity of 132 mAh g(-1) , a cell potential of 3.5 V, and a lifetime exceeding more than 250 cycles.

© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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