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Dalton Trans. 2014 May 21;43(19):6994-7. doi: 10.1039/c4dt00222a. Epub 2014 Apr 4.

Dehydration-triggered magnetic phase conversion in the porous Cu(II)Mn(III) metal-organic framework.

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  • 1Department of Chemistry, Research Institute for Natural Sciences, Korea University, Seoul 136-713, Korea. cshong@korea.ac.kr.

Abstract

Dehydration of the three-dimensional Cu(II)-Mn(III) coordination network undergoes a dramatic magnetic phase transformation from a paramagnetic state to a long-range magnetic ordered phase with glassy behavior. The gas adsorption behavior and re-entrant spin glass character are uniquely apparent in the dehydrated sample.

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