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J Org Chem. 2014 Apr 18;79(8):3581-6. doi: 10.1021/jo500405v. Epub 2014 Apr 3.

Hemicarceplexes modify the solubility and reduction potentials of C60.

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  • 1Department of Chemistry, National Taiwan University , Taipei, Taiwan, R.O.C.

Abstract

A highly stable C60-incarcerated hemicarceplex, which retains its molecular integrity after heating at 523 K in air for at least 3 h, significantly increases the solubility of C60 in nonpolar solvents and increases the reduction potentials of the entrapped fullerene. Modification with [(η(5)-C5Me5)Ru(II)](+) dramatically increases the solubility of this hemicarceplex in polar, protic solvents (e.g., MeOH).

PMID:
24665822
[PubMed - indexed for MEDLINE]
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